trans-Diaquabis(3-hydroxybenzoato-kappa O-1)bis(nicotinamide-kappa N-1)copper(II)


Sahin O., Bueyuekguengoer O., Koese D. A. , Necefoglu H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.63, 2007 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 63
  • Publication Date: 2007
  • Doi Number: 10.1107/s0108270107047142
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS

Abstract

The title compound,[Cu(C7H5O3)(2)(C6H6N2O)(2)(H2O)(2)], is a two-dimensional hydrogen-bonded supramolecular complex. The Cu-II ion resides on a centre of symmetry and is in an octahedral coordination environment comprising two pyridine N atoms, two carboxylate O atoms and two O atoms from water molecules. Intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds produce R-2(2)(4), R-2(2)(8) and R-2(2)(15) rings which lead to one-dimensional polymeric chains. An extensive two-dimensional network of N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi interactions are responsible for crystal stabilization.