Electrochemistry of poly(5-phenyl dipyrromethane) and its characterization

BOLAT G., Kuralay F., TEMELLİ B., ÜNALEROĞLU C., ABACI S.

POLYMER BULLETIN, vol.72, no.4, pp.867-879, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 72 Issue: 4
  • Publication Date: 2015
  • Doi Number: 10.1007/s00289-015-1311-x
  • Journal Name: POLYMER BULLETIN
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.867-879
  • Hacettepe University Affiliated: Yes

Abstract

In this work, electropolymerization of 5-phenyl dipyrromethane (DPM) and electrochemical behavior of the obtained polymer were performed. The monomer was electropolymerized in a solution of DPM and 0.1 M tetra-n-butyl ammonium perchlorate/dichloromethane supporting electrolyte/solvent solution system on a Pt electrode by cyclic voltammetry technique. The polymeric film was then characterized by scanning electron microscopy, atomic force microscopy, fourier transform infrared-attenuated total reflectance, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and alternative current impedance techniques.