Electrochemistry of poly(5-phenyl dipyrromethane) and its characterization
POLYMER BULLETIN, vol.72, no.4, pp.867-879, 2015 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 72 Issue: 4
- Publication Date: 2015
- Doi Number: 10.1007/s00289-015-1311-x
- Journal Name: POLYMER BULLETIN
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.867-879
- Hacettepe University Affiliated: Yes
Abstract
In this work, electropolymerization of 5-phenyl dipyrromethane (DPM) and electrochemical behavior of the obtained polymer were performed. The monomer was electropolymerized in a solution of DPM and 0.1 M tetra-n-butyl ammonium perchlorate/dichloromethane supporting electrolyte/solvent solution system on a Pt electrode by cyclic voltammetry technique. The polymeric film was then characterized by scanning electron microscopy, atomic force microscopy, fourier transform infrared-attenuated total reflectance, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and alternative current impedance techniques.