Vibrational Spectroscopic Studies on the T-d-type Clathrates: M(dl-Propylenediamine)M '(CN)(4)center dot nG

Bayrak C.

ASIAN JOURNAL OF CHEMISTRY, vol.22, no.5, pp.3576-3582, 2010 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 22 Issue: 5
  • Publication Date: 2010
  • Journal Name: ASIAN JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3576-3582
  • Hacettepe University Affiliated: Yes

Abstract

In this study, M(dl-propylenediamine)M '(CN)4 center dot nG (M = Mn, M ' = Zn or Hg, M = Cd, M ' = Hg: 1 25 <= n <= 1 5, G = thiophene) clathrates of dl-propylenediamine (pn) were prepared and their FT-IR and FT- Raman spectra were investigated The infrared spectra of the clathrates were recorded in the range 4000-50 cm(-1) and FT-Raman spectra of the clathrate (Cd-pn-Hg-Thi) was recorded 4000-50 cm(-1) and its fundamental vibrational wavenumbers were obtained.