Solubility profiles of poly(ethylene glycol)/solvent systems, I: Qualitative comparison of solubility parameter approaches

Ozdemir C., Guener A.

EUROPEAN POLYMER JOURNAL, vol.43, no.7, pp.3068-3093, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Review
  • Volume: 43 Issue: 7
  • Publication Date: 2007
  • Doi Number: 10.1016/j.eurpolymj.2007.02.022
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3068-3093
  • Hacettepe University Affiliated: No


Solubility of systems involving four different molecular weights of poly(ethylene glycol) (PEG) in tetrahydrofuran (THF), chloroform, dimethylsulfoxide (DMSO), methanol and water have been investigated by different algorithmic approaches as the mathematical application of the "like dissolves like" principle. In this study, the solubility parameters and their components for PEG and solvents have been evaluated by using of atomic group contribution methods; Small, van Krevelen-Hoftyzer (VKH), Hoy and Breitkreutz methods, respectively. Then their 2-dimensional graphs (Bagley, Henry and Hoernschemeyer diagrams) and 3-dimensional graph (Hansen diagram) have been drawn by creating the solubility profiles of the polymer in selected solvents. The dissolving capability of these solvents has been discussed. In addition the solubility parameters have been calculated by use of the van der Waals volume in the selected molecule or repeating unit of the polymer instead of the molar volume which is used in atomic group contribution methods (Askadskii approach). Surface tensions of the polymer and solvent systems have been calculated with this method and solubility criteria of PEG have been explained after a serial calculation steps. In addition, influence of molecular weight of PEG on solubility has been also analyzed. As a consequence of algorithmic calculations, THF has been determined as the best solvent whereas water is found to be the weakest solvent for polymer/solvent systems. (c) 2007 Elsevier Ltd. All rights reserved.