Bis{(mu-acetato)[mu-bis(salicylidene)-1,3-propanediaminato]copper(II)}cadmium(II) dioxane solvate

Ercan F., Ulku D., Atakol O., Dincer F.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.54, pp.1787-1790, 1998 (SCI-Expanded) identifier identifier


The title compound, [Cd{Cu(CH3CO2)(C17H16N2O2)}(2)].- C4H8O2, is a linear hetero-trinuclear complex with a central Cd-II ion and lies on an inversion centre. This central Cd-II ion has an irregular octahedral coordination. The coordination around the Cd-II ion involves four O atoms from two N,N'-bis(salicylidene)- 1,3-propane-diaminato (SALPD(2-)) and two acetate ligands. The terminal Cu-II ions have an irregular square-pyramidal coordination. The coordination of the terminal Cu-II atom is provided by the two O and two N atoms from an SALPD(2-) ligand and one O atom from an acetate Ligand. The Cd ... Cu bridging distance is 3.244(3) Angstrom.