Bis{(mu-acetato)[mu-bis(salicylidene)-1,3-propanediaminato]copper(II)}cadmium(II) dioxane solvate

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Atıf İçin Kopyala

Ercan F., Ulku D., Atakol O., Dincer F.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.54, ss.1787-1790, 1998 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 54
• Basım Tarihi: 1998
• Doi Numarası: 10.1107/s010827019800835x
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1787-1790
• Hacettepe Üniversitesi Adresli: Evet

Özet

The title compound, [Cd{Cu(CH3CO2)(C17H16N2O2)}(2)].- C4H8O2, is a linear hetero-trinuclear complex with a central Cd-II ion and lies on an inversion centre. This central Cd-II ion has an irregular octahedral coordination. The coordination around the Cd-II ion involves four O atoms from two N,N'-bis(salicylidene)- 1,3-propane-diaminato (SALPD(2-)) and two acetate ligands. The terminal Cu-II ions have an irregular square-pyramidal coordination. The coordination of the terminal Cu-II atom is provided by the two O and two N atoms from an SALPD(2-) ligand and one O atom from an acetate Ligand. The Cd ... Cu bridging distance is 3.244(3) Angstrom.