EPDM Elastomer and Biothermoplastic Polyester-based Silicate-layered Multifunctional Nanocomposites Incorporated with Poly(MA-alt--olefin)-g-APTS-SiO2 NPs and PP-g-MA by Reactive Extrusion Nanotechnology

Rzayev Z. M. O., Gocmen B. A., DEMİRCAN BOZDOĞAN D., Kibarer G.

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, vol.56, no.17, pp.1839-1856, 2017 (SCI-Expanded) identifier identifier

Abstract

Multifunctional polymer blend nanocomposites consisting EPDM elastomer as a matrix polymer, bioengineering polyesters (PLA and PCL), PP-g-MA compatibilizer and covalently encapsulated colloidal alternating reactive copolymer-g--aminopropyl trimethoxysilane-silica nanoparticles as reactive compatibilizer nanofillers, and organoclay (reactive ODA-MMT and complexable DMDA-MMT) nanofillers were fabricated in melt by a one-step reactive extrusion nanotechnology. The effects of bioengineering polyesters and their molecular mass, origin of organology, and reactive PP-g-MA compatibilizer were evaluated. Unique nanostructures, lower particle sizes and crystallinity, SEM-TEM morphologies, higher thermal behaviors, good mechanical and rheological properties of thermoplastic multifunctional nanocomposites were evaluated.