Akademik Veri Yönetim Sistemi
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, cilt.635, sa.11, ss.1626-1632, 2009 (SCI-Expanded)
Solution Combustion Synthesis (SCS) and Conventional Ceramic Process (CCP) were applied for the preparation of magnesium pyroborate (Mg2B2O5) from Mg(NO3)(2)center dot 6H(2)O and H3BO3. Structural and morphological properties of the products were comparatively examined by XRD and FT-IR spectroscopic measurements as well as SEM and BET techniques. The effects of synthesis conditions on the properties of products were investigated throughly by optimizing the B/Mg molar ratio and reaction duration in CCP and by optimizing the fuel (carbohydrazide) quantity in SCS, Pure Mg2B2O5 (triclinic suanite) was obtained by thermal treatment in CCP employing a B/Mg molar ratio of 3: 1. It was found that the fuel must be in close proximity to the stoichiometric requirements in order to obtain the desired product in highly crystalline form from SCS. The Mg2B2O5 samples obtained by both methods exhibited similar structural properties but different morphologies.