Spectroscopic Studies and Crystal Structure of (Z)-6-[(2-hydroxyphenylamino)methylene]-2-methoxycyclohexa-2,4-dienone


Uenver H., YILDIZ M., Kiraz A., Oezgen O.

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, vol.39, no.1, pp.17-23, 2009 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 39 Issue: 1
  • Publication Date: 2009
  • Doi Number: 10.1007/s10870-008-9412-0
  • Journal Name: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.17-23

Abstract

The Schiff base (Z)-6-[(2-hydroxyphenylamino) methylene]-2-methoxycyclohexa-2,4-dienone has been synthesized from the reaction of 2-aminophenol with 2-hydroxy-3-methoxybenzaldehyde. The title compound has been characterized by elemental analysis, FT-IR, H-1-NMR, C-13-NMR and UV-Visible techniques. The structure of the title compound also was determined crystallographically. The crystal structure has been solved by direct methods and refined by full-matrix least squares. The title compound crystallize in the monoclinic space group P2(1)/c with a = 10.438(1), b = 8.851(1), c = 12.746(1) angstrom, beta = 95.72(1)degrees, V = 1171.7(2) angstrom(3), D-x = 1.379 g cm(-3), respectively (R1 = 0.0522 and wR2 = 0.126 for 1442 reflections [I > 2 sigma(1)]).