Crystal structure analysis of Bis{(N,N '-dimethylformamide)-[mu-bis-N,N '-(2-oxybenzyl)-1,3-propanediaminato](mu-asetato)nickel(II)}nickel(II)

YILDIRIM L., Atakol O.

CRYSTAL RESEARCH AND TECHNOLOGY, cilt.37, sa.12, ss.1352-1359, 2002 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Sayı: 12
  • Basım Tarihi: 2002
  • Dergi Adı: CRYSTAL RESEARCH AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1352-1359
  • Hacettepe Üniversitesi Adresli: Evet

Özet

The title compound, a homotrinuclear Ni-II complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17H20N2O3) (C3H7NO)}(2)], was identified using elemental analysis, thermal analysis, IR spectroscopy and x-ray diffraction techniques, It was established that although some bond lengths and angles changed with respect to previous complexes, the Ni...Ni distance was approximately the same.