Crystal structure analysis of Bis{(N,N '-dimethylformamide)-[mu-bis-N,N '-(2-oxybenzyl)-1,3-propanediaminato](mu-asetato)nickel(II)}nickel(II)
CRYSTAL RESEARCH AND TECHNOLOGY, vol.37, no.12, pp.1352-1359, 2002 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 37 Issue: 12
- Publication Date: 2002
- Journal Name: CRYSTAL RESEARCH AND TECHNOLOGY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.1352-1359
- Hacettepe University Affiliated: Yes
Abstract
The title compound, a homotrinuclear Ni-II complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17H20N2O3) (C3H7NO)}(2)], was identified using elemental analysis, thermal analysis, IR spectroscopy and x-ray diffraction techniques, It was established that although some bond lengths and angles changed with respect to previous complexes, the Ni...Ni distance was approximately the same.