Vibrational Spectroscopic Studies on the T-d-type N,N '-dimethylethylenediamine(II)tetracyanometallate(II) Benzene Clathrates

Bayrak C.

ASIAN JOURNAL OF CHEMISTRY, vol.22, no.5, pp.3734-3740, 2010 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 22 Issue: 5
  • Publication Date: 2010
  • Journal Name: ASIAN JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.3734-3740
  • Hacettepe University Affiliated: Yes

Abstract

FT-IR spectra of Mn(DMEDA)M(CN)(4) C6H6, (M = Zn. Cd or Hg, DMEDA = N,N'-dimethylethylenediamine) and FT-IR and FT-Raman spectra of Cd(DMEDA)M(CN)(4) C6H6(M = Cd or Hg) are reported. All the vibrational modes of coordinated DMEDA are characterized The spectral features suggest that these compounds are similar in structure to the Hofmann-T-d-type clathrates.