The synthesis, structure and thermal decomposition of some Cu(II) complexes with NNN type ligands and thiocyanate anion

Tastekin M., Arici C., Svoboda I., Emregul K. C. , Kurtaran R., Atakol O., ...More

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.222, no.5, pp.255-258, 2007 (Peer-Reviewed Journal) identifier identifier

  • Publication Type: Article / Article
  • Volume: 222 Issue: 5
  • Publication Date: 2007
  • Doi Number: 10.1524/zkri.2007.222.5.255
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.255-258

Abstract

Three new complexes were prepared from Cu(H) thiocyanate and bis-2,6(pyrazol-1-yl) pyridine (pp), bis-2,6(3,5-dimethylpyrazol-1-yl) pyridine (dmpp) and 2(3,5-dimethylpyrazol-1-yl)-6-(pyrazol-1-yl) pyridine (mpp). One of the complex structures was characterized using X-ray diffraction. Cu(II), within the NS coordination sphere, was seen to form a square pyramid and trigonal bipyramid structure. Decomposition of the three complexes was analyzed thermogravimetrically. Results showed the complexes to be more stable with comparison to Cu(SCN)(2).