The synthesis, structure and thermal decomposition of some Cu(II) complexes with NNN type ligands and thiocyanate anion

Tastekin M., Arici C., Svoboda I., Emregul K. C., Kurtaran R., Atakol O., ...More

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.222, no.5, pp.255-258, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 222 Issue: 5
  • Publication Date: 2007
  • Doi Number: 10.1524/zkri.2007.222.5.255
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.255-258
  • Hacettepe University Affiliated: No

Abstract

Three new complexes were prepared from Cu(H) thiocyanate and bis-2,6(pyrazol-1-yl) pyridine (pp), bis-2,6(3,5-dimethylpyrazol-1-yl) pyridine (dmpp) and 2(3,5-dimethylpyrazol-1-yl)-6-(pyrazol-1-yl) pyridine (mpp). One of the complex structures was characterized using X-ray diffraction. Cu(II), within the NS coordination sphere, was seen to form a square pyramid and trigonal bipyramid structure. Decomposition of the three complexes was analyzed thermogravimetrically. Results showed the complexes to be more stable with comparison to Cu(SCN)(2).