The synthesis, structure and thermal decomposition of some Cu(II) complexes with NNN type ligands and thiocyanate anion

Tastekin M., Arici C., Svoboda I., Emregul K. C., Kurtaran R., Atakol O., ...Daha Fazla

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.222, sa.5, ss.255-258, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 222 Sayı: 5
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1524/zkri.2007.222.5.255
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.255-258
  • Hacettepe Üniversitesi Adresli: Hayır

Özet

Three new complexes were prepared from Cu(H) thiocyanate and bis-2,6(pyrazol-1-yl) pyridine (pp), bis-2,6(3,5-dimethylpyrazol-1-yl) pyridine (dmpp) and 2(3,5-dimethylpyrazol-1-yl)-6-(pyrazol-1-yl) pyridine (mpp). One of the complex structures was characterized using X-ray diffraction. Cu(II), within the NS coordination sphere, was seen to form a square pyramid and trigonal bipyramid structure. Decomposition of the three complexes was analyzed thermogravimetrically. Results showed the complexes to be more stable with comparison to Cu(SCN)(2).