Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

Ibisoglu, Hanife; Ciftci, Goenuel; Kilic, Adem; Tanriverdi, Esra; Un, Ilker; Dal, Hakan; HÖKELEK, TUNCER

doi:10.1007/s12039-009-0014-y

Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

Ibisoglu H., Ciftci G. Y., Kilic A., Tanriverdi E., Un I., Dal H., ...Daha Fazla

JOURNAL OF CHEMICAL SCIENCES, cilt.121, sa.2, ss.125-135, 2009 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 121 Sayı: 2
Basım Tarihi: 2009
Doi Numarası: 10.1007/s12039-009-0014-y
Dergi Adı: JOURNAL OF CHEMICAL SCIENCES
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.125-135
Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
Hacettepe Üniversitesi Adresli: Evet

Özet

Nucleophilic substitution reactions of N4P4Cl8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, H-1 and P-31 NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.