Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene


Ibisoglu H., Ciftci G. Y. , Kilic A., Tanriverdi E., Un I., Dal H., ...Daha Fazla

JOURNAL OF CHEMICAL SCIENCES, cilt.121, sa.2, ss.125-135, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 121 Konu: 2
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s12039-009-0014-y
  • Dergi Adı: JOURNAL OF CHEMICAL SCIENCES
  • Sayfa Sayıları: ss.125-135

Özet

Nucleophilic substitution reactions of N4P4Cl8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, H-1 and P-31 NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.