5,10,15,20-TETRAKIS(P-CHLOROPHENYL)-PORPHYRIN


HOKELEK T. , ULKU D., GUNDUZ N., HAYVALI M., KILIC Z.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.49, ss.1667-1670, 1993 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 49
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1107/s0108270193000782
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Sayfa Sayıları: ss.1667-1670

Özet

The title molecule, 2,7,12,17-tetrakis(4-chloro-phenyl)-21,22,23,24-tetraazapentacyclo[I 6.2. 1.1(3,6.-1(8,11.)1(13,16]tetracosa-1,3(22),4,6,8,10,12,14,16(4),17,-19-undecaene, is crystallographically centrosymmetric and the dihedral angle between the two pyrrole ring planes is 5.0 (4)-degrees . The molecular structure is a consequence of steric hinderances between the a-H atoms of the pyrrole and the ortho-H atoms of the phenyl rings. The dihedral angles between the pyrrole and phenyl rings are 54.8 (4) and 111. 1 (3)-degrees, respectively. The sums of the angles around meso-C atoms are -360-degrees and the average bond length between meso and adjacent macrocyclic ring C atoms is 1.398 (6) angstrom.