Amine functionalization of cellulose surface grafted with glycidyl methacrylate by gamma-initiated RAFT polymerization


BARSBAY M., GUVEN O., KODAMA Y.

RADIATION PHYSICS AND CHEMISTRY, vol.124, pp.140-144, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 124
  • Publication Date: 2016
  • Doi Number: 10.1016/j.radphyschem.2015.12.015
  • Journal Name: RADIATION PHYSICS AND CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.140-144
  • Keywords: Poly(glycidyl methacrylate) (PGMA), Cellulose functionalization, Radiation-induced grafting, RAFT polymerization, Ethylenediamine (EDA), IMMOBILIZATION, PHEMA
  • Hacettepe University Affiliated: Yes

Abstract

This study presents the functionalization of poly(glycidyl methacrylate) (PGMA) grafted cellulose filter paper by a model compound, ethylenediamine (EDA), through the epoxy groups of PGMA. Cellulose based copolymers were prepared via the radiation-induced and RAFT-mediated graft polymerization. The samples were characterized by ATR-FTIR spectroscopy, X-ray photoelectron spectroscopy (XPS), elemental analysis, contact angle measurements and scanning electron microscopy (SEM). An efficient modification density of around 1 mmol EDA/mg copolymer was attained within ca. 8 h, indicating that chemical composition of well-defined copolymers may further be tuned by appropriately selecting the reactive agents for use in many emerging fields. (C) 2015 Elsevier Ltd. All rights reserved.