Preparation and characterization of Co(II), Ni(II) and Cu(II) complexes of a ligand containing 1,3,4-thiadiazole groups

Ozturk O. F., Cansiz A., Koparir M.

TRANSITION METAL CHEMISTRY, vol.32, no.2, pp.224-227, 2007 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 32 Issue: 2
  • Publication Date: 2007
  • Doi Number: 10.1007/s11243-006-0159-1
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.224-227
  • Hacettepe University Affiliated: No

Abstract

(1R,2R)-1,2-bis-(5-amino-1,3,4-thiadiazole-2-yl)ethane-1,2-diol (L) has been prepared by the reaction of thiosemicarbazide with (2R,3R)-(+)-tartaric acid (I) and phosphorous oxychloride, and its complexes with Co(II), Ni(II) and Cu(II) have been obtained. The structures of the ligand and its complexes have been established by i.r., H-1- and C-13-n.m.r. spectra, u.v.-vis-nir spectroscopy, elemental analyses, T.g.-D.t.a. and magnetic susceptibility measurements.