(Benzoylacetonato)chloro(1,10-phenanthroline)copper(II)


Elerman Y., Kara H., Ozcan S. , Kendi E.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.56, pp.950-951, 2000 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 56
  • Publication Date: 2000
  • Doi Number: 10.1107/s0108270100007411
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Page Numbers: pp.950-951

Abstract

The crystal structure of the title compound, chloro(1,10-phenanthroline-N,N')(1-phenyl-1,3-butanedionato-O,O')copper(II), [CuCl(C10H9O2)(C12H8N2)], has been determined. The Cu II ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)/ 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Angstrom, respectively.