Spectroscopic studies on the interaction of ofloxacin with metals

Sagdinc S., Bayari S.

JOURNAL OF MOLECULAR STRUCTURE, cilt.691, ss.107-113, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 691
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1016/j.molstruc.2003.11.053
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.107-113
  • Anahtar Kelimeler: quinolone, metal-ofloxacin complexes, Fourier transform infrared spectra, PM3 calculations, CRYSTAL-STRUCTURE, COMPLEXES
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Several coordination compounds (1:1) formed between alkaline earth metal cations [Mg(II), Ca(II) and Ba(II)] and transition metal ions [Co(II), Ni(II) and Zn(II)] with oflocaxin were synthesized. The compounds have been characterized using elemental analysis, Fourier transform infrared (FT-IR) spectroscopy and H-1 NMR spectra. The solid state samples of all complexes have been measured within the range 4000-400 cm(-1). Based on normal mode calculations for complexes, the assignments of bands observed in FT-IR spectra of studied compounds have been done. Some significant differences in vibrational structure have been observed and discussed. The frequencies and intensities of some bands of the ofloxacin depend systematically on the second ionization potential of the metals. (C) 2003 Elsevier B.V. All rights reserved.