Cloud point extraction of aluminum (III) in water samples and determination by electrothermal atomic absorption spectrometry, flame atomic absorption spectrometry and UV-visible spectrophotometry

ŞATIROĞLU N., Tokgoz İ.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, vol.90, no.7, pp.560-572, 2010 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 90 Issue: 7
  • Publication Date: 2010
  • Doi Number: 10.1080/03067310903276266
  • Journal Name: INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.560-572
  • Keywords: cloud point extraction, aluminum, electrothermal atomic absorption spectrometry, flame atomic absorption spectrometry, UV-visible spectrophotometry, SOLID-PHASE EXTRACTION, TRACE ALUMINUM, PARENTERAL SOLUTIONS, PRECONCENTRATION, SEPARATION, FRACTIONS
  • Hacettepe University Affiliated: Yes

Abstract

Cloud point extraction was applied as a preconcentration step for the determination of trace level of Al(III) in water samples with electrothermal atomic absorption spectrometry (ETAAS), flame atomic absorption spectrometry (FAAS) and UV-visible spectrophotometry. The aluminum was extracted as aluminum-Eriochrome Cyanine R (ECR) complex, at pH 6 by micelles of the non-ionic surfactant octylphenoxypolyethoxyethanol (Triton X-114). The investigations showed that the same CPE procedure can be used for different detection techniques. The results obtained from these techniques were evaluated. Under the optimal conditions, limit of detection obtained with ETAAS, FAAS and UV-visible spectrophotometry were 0.03 ng mL(-1), 0.06 mu g mL(-1) and 0.01 mu g mL(-1), respectively. The accuracy of the procedure was tested by analysing certified reference material. The method was successfully applied to determination of aluminum in water samples and dialysis fluid.