Diaquabis(N,N-diethylnicotinamide-N-1)bis(2-hydroxybenzoato-O)cobalt(II)


Hokelek T. , NECEFOGLU H.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.53, ss.187-189, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 53
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1107/s0108270196013170
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
  • Sayfa Sayıları: ss.187-189

Özet

The title monomeric centrosymmetric cobalt complex, [Co(C7H5O3)(2)(C10H14N2O)(2)(H2O)(2)], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All Ligands are coordinated to the Co atom as monodentate Ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) Angstrom. The water molecules are hydrogen bonded to the carboxyl O atoms [O ... O 2.687 (5) Angstrom].