Radiation synthesis and characterization of new hydrogels based on acrylamide copolymers cross-linked with 1-allyl-2-thiourea


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ŞAHİNER N., MALCI S., Celikbicak O., KANTOĞLU Ö., Salih B.

RADIATION PHYSICS AND CHEMISTRY, cilt.74, sa.2, ss.76-85, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74 Sayı: 2
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.radphyschem.2005.02.002
  • Dergi Adı: RADIATION PHYSICS AND CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.76-85
  • Anahtar Kelimeler: acrylamide, 1-allyl-2-thiourea, hydrogets, thermogravimetry, gamma-irradiation, swelling, characterization, HEAVY-METALS, ADSORPTION, ACID), WATER, COMPLEXES, SPECTRA, GEL, PH
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Poly(acrylamide-1-allyl-2-thiourea) hydrogels, Poly(AA-AT), were synthesized by gamma irradiation using Co-60 gamma source in different irradiation dose and at different 1-allyl-2-thiourea content in the monomer mixture. For the characterization of the hydrogels, Fourier transform infrared spectrometer (FT-IR), thermogravimetric analyzer (TGA), elemental analyzer and the swellability of the hydrogels were used. It was noted that 1-allyl-2-thiourea in the synthesized hydrogels was increased by the increasing the content of the 1-allyl-2-thiourea in the irradiation monomer mixture and increasing the radiation dose for the hydrogel synthesis. (C) 2005 Elsevier Ltd. All rights reserved.

Poly(acrylamide-1-allyl-2-thiourea) hydrogels, Poly(AA-AT), were synthesized by gamma irradiation using 60Co γγ source in different irradiation dose and at different 1-allyl-2-thiourea content in the monomer mixture. For the characterization of the hydrogels, Fourier transform infrared spectrometer (FT-IR), thermogravimetric analyzer (TGA), elemental analyzer and the swellability of the hydrogels were used. It was noted that 1-allyl-2-thiourea in the synthesized hydrogels was increased by the increasing the content of the 1-allyl-2-thiourea in the irradiation monomer mixture and increasing the radiation dose for the hydrogel synthesis.