Silicon and Chlorine Substituted Unsaturated Polymers: ROMP of (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane via Mo-based catalyst


Karabulut S., ŞAHİN V. , ÖZTÜRK B. Ö. , İmamoglu Y.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.19, ss.570-574, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 19 Konu: 4
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s10904-009-9302-8
  • Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Sayfa Sayıları: ss.570-574

Özet

Ring opening metathesis polymerization (ROMP) of a norbornene derivative that contains silicon and chlorine, (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane, by using electrochemically produced active catalyst species (MoCl(5)-e(-)-Al-CH(2)Cl(2)) was investigated. Silicon and chlorine containing unsaturated polymer was characterized by (1)H, (13)C, and (29)Si-NMR and FTIR spectroscopy. The thermal behavior of the polymer was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).