Silicon and Chlorine Substituted Unsaturated Polymers: ROMP of (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane via Mo-based catalyst

Karabulut, Solmaz; Şahin, VOLKAN; Öztürk, BENGİ; İmamoglu, Yavuz

doi:10.1007/s10904-009-9302-8

Silicon and Chlorine Substituted Unsaturated Polymers: ROMP of (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane via Mo-based catalyst

Karabulut S., Şahin V., Öztürk B. Ö., İmamoglu Y.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, cilt.19, sa.4, ss.570-574, 2009 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 19 Sayı: 4
Basım Tarihi: 2009
Doi Numarası: 10.1007/s10904-009-9302-8
Dergi Adı: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Sayfa Sayıları: ss.570-574
Hacettepe Üniversitesi Adresli: Evet

Özet

Ring opening metathesis polymerization (ROMP) of a norbornene derivative that contains silicon and chlorine, (bicyclo[2,2,1]hept-5-en-2-yl)ethylchlorodimethylsilane, by using electrochemically produced active catalyst species (MoCl(5)-e(-)-Al-CH(2)Cl(2)) was investigated. Silicon and chlorine containing unsaturated polymer was characterized by (1)H, (13)C, and (29)Si-NMR and FTIR spectroscopy. The thermal behavior of the polymer was determined by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).