Synthesis, crystal structure and electrochemical behaviour of water soluble Schiff bases

Tatar L., Nazir H., Gumuser M., Kale C., Atakol O.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.220, sa.7, ss.639-642, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 220 Sayı: 7
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1524/zkri.220.7.639.67102
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.639-642
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Four water soluble Schiff bases were prepared from the reaction of salicylaldehyde and 2-hydroxy-1-naphtaldehyde with 2-amino-2-methyl-1,3-dihydroxy propane and 2-amino-2-methoxy-1,3-dihydroxy propane. Two of the Schiff bases were characterized using elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In addition cyclic voltammetric studies were performed. The Schiff bases C11H5NO4 (II) and C15H17NO3 (III) crystalize in monoclinic space group P2(1)/c with unit cell dimensions a = 10.499(2), b = 8.725(2), c = 12.635(10) angstrom, beta = 101.649(11); a = 14.579(8) b = 9.834(13), c = 9.542(5) angstrom, beta = 107.559(5) respectively.