P,P-dichloro-N-(dichlorophosphinoyl)-P-(diisopropylamino)monophosphazene
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, vol.54, pp.523-525, 1998 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 54
- Publication Date: 1998
- Doi Number: 10.1107/s0108270197016983
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, Compendex, EMBASE, INSPEC, MEDLINE
- Page Numbers: pp.523-525
- Hacettepe University Affiliated: Yes
Abstract
The title compound, C6H14Cl4N2OP2, has an acyclic monophosphazene skeleton and a bulky diisopropylamino side group. The bulky substituent is instrumental in determining the molecular geometry. The P-N bonds have neither single-nor double-bond character and are substantially shorter than the ideal P-N single bond. The P-N-P angle [134.0 (2)degrees] is similar to the angle found in cyclotetraphosphazenes, but wider than that in cyclotriphosphazenes.