P,P-dichloro-N-(dichlorophosphinoyl)-P-(diisopropylamino)monophosphazene


Hokelek T. , KILIC Z., DAL H.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.54, ss.523-525, 1998 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 54
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1107/s0108270197016983
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
  • Sayfa Sayıları: ss.523-525

Özet

The title compound, C6H14Cl4N2OP2, has an acyclic monophosphazene skeleton and a bulky diisopropylamino side group. The bulky substituent is instrumental in determining the molecular geometry. The P-N bonds have neither single-nor double-bond character and are substantially shorter than the ideal P-N single bond. The P-N-P angle [134.0 (2)degrees] is similar to the angle found in cyclotetraphosphazenes, but wider than that in cyclotriphosphazenes.