{2-[(2-hydroxy-5-methylphenyl)iminomethyl]-4,6-dinitrophenolato(2-)-O,N,O′}tris(3-methylpyridine-N)nickel(II)

---

Copy For Citation

Tahir M., Ulku D., ATAKOL O., Basgut O.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, pp.623-625, 1998 (SCI-Expanded)

• Publication Type: Article / Article
• Publication Date: 1998
• Doi Number: 10.1107/s0108270197016545
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Page Numbers: pp.623-625
• Hacettepe University Affiliated: No

Abstract

In the title compound, [Ni(C14H9N3O6)(C6H7N)(3)], the coordination polyhedron around the Ni-11 atom is a slightly distorted octahedron, with one N atom of the tridentate ligand and three N atoms of three monodentate ligands forming the equatorial plane. The apical positions are occupied by the two phenolic O atoms of the tridentate ligand. The Ni-O distances are 2.013 (2) and 2.008(2)Angstrom, and the Ni-N distances range from 2.043(2) to 2.168(3) Angstrom. The cis bond angles at Ni-11 range from 82.75 (9) to 96.2 (1)degrees. There are intramolecular, as well as intermolecular, hydrogen bonds in the structure.