{2-[(2-hydroxy-5-methylphenyl)iminomethyl]-4,6-dinitrophenolato(2-)-O,N,O′}tris(3-methylpyridine-N)nickel(II)
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, ss.623-625, 1998 (SCI-Expanded)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 1998
- Doi Numarası: 10.1107/s0108270197016545
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
- Sayfa Sayıları: ss.623-625
- Hacettepe Üniversitesi Adresli: Hayır
Özet
In the title compound, [Ni(C14H9N3O6)(C6H7N)(3)], the coordination polyhedron around the Ni-11 atom is a slightly distorted octahedron, with one N atom of the tridentate ligand and three N atoms of three monodentate ligands forming the equatorial plane. The apical positions are occupied by the two phenolic O atoms of the tridentate ligand. The Ni-O distances are 2.013 (2) and 2.008(2)Angstrom, and the Ni-N distances range from 2.043(2) to 2.168(3) Angstrom. The cis bond angles at Ni-11 range from 82.75 (9) to 96.2 (1)degrees. There are intramolecular, as well as intermolecular, hydrogen bonds in the structure.