Synthesis and characterization of bis(nicotinamide) m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II)

Kose, D.; Necefoglu, H.

doi:10.1007/s10973-007-8712-5

Synthesis and characterization of bis(nicotinamide) m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II)

Atıf İçin Kopyala

Kose D. A., Necefoglu H.

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, cilt.93, sa.2, ss.509-514, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 93 Sayı: 2
Basım Tarihi: 2008
Doi Numarası: 10.1007/s10973-007-8712-5
Dergi Adı: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.509-514
Hacettepe Üniversitesi Adresli: Evet

Özet

The mixed-ligand m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II) with nicotinamide were synthesized and characterized. The chemical, FT IR and UV-vis spectrophotometric, thermal and mass spectral analyses, magnetic susceptibility measurements revealed that the compounds contain two water molecules, two m-hydroxybenzoate (m-hba) and two nicotinamide (na) ligands per formula unit. m-Hydroxybenzoate and nicotinamide ligands bind to the metal atoms monodentately through their acidic oxygen and pyridinic nitrogen atoms, respectively. The thermal decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data.