Tetraaquabis[4-(dimethylamino)benzoato-kappa O]manganese(II) dihydrate

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Hokelek T., NECEFOGLU H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.63, 2007 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 63
• Publication Date: 2007
• Doi Number: 10.1107/s1600536807007799
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
• Hacettepe University Affiliated: Yes

Abstract

The title Mn-II complex, [Mn(C9H10NO2)(2)(H2O)(4)](.)2H(2)O, is monomeric and centrosymmetric. It contains two 4-dimethyl-aminobenzoate ligands, four coordinated and two uncoordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two water O atoms in the axial positions. In the crystal structure, intra- and intermolecular O-(HO)-O-... hydrogen bonds link the molecules into chains.