Tetraaquabis[4-(dimethylamino)benzoato-kappa O]manganese(II) dihydrate


Hokelek T. , NECEFOGLU H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.63, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1107/s1600536807007799
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

The title Mn-II complex, [Mn(C9H10NO2)(2)(H2O)(4)](.)2H(2)O, is monomeric and centrosymmetric. It contains two 4-dimethyl-aminobenzoate ligands, four coordinated and two uncoordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two water O atoms in the axial positions. In the crystal structure, intra- and intermolecular O-(HO)-O-... hydrogen bonds link the molecules into chains.