Grafting of N,N-dimethylaminoethyl methacrylate from PE/PP nonwoven fabric via radiation-induced RAFT polymerization and quaternization of the grafts


MADRID J. F. , BARSBAY M. , ABAD L., GUVEN O.

RADIATION PHYSICS AND CHEMISTRY, cilt.124, ss.145-154, 2016 (SCI İndekslerine Giren Dergi) identifier identifier

Özet

Radiation induced grafting method is one of the most promising grafting techniques and it works successfully together with the reversible addition fragmentation chain transfer (RAFT) polymerization, one of the most prominent controlled free-radical polymerization (CRP) methods. This study reports grafting of N,N-dimethylaminoethyl methacrylate (DMAEMA) from the surface of polyethylene/polypropylene nonwoven fabric (PE/PP NWF) by the combination of radiation-induced initiation and the RAFT polymerization technique. Effects of monomer concentration, absorbed dose and solvent choice on the grafting yield have been investigated. The grafted NWF's were characterized by ATR-FTIR, XPS, SEM, EDX and thermal analysis methods. The results indicated that surface properties were completely altered after grafting compared to pristine PE/PP even for those with very low degree of PDMAEMA grafting. Free homopolymers in solution have been analyzed by GPC in order to obtain information about the grafts. The PDMAEMA grafts on the fabric surfaces were later quaternized with dimethyl sulfate to yield positively charged surfaces that were tested for antibacterial properties. (C) 2016 Elsevier Ltd. All rights reserved.