Crystal structure analysis of Bis{(N,N′-dimethylformamide)-[μ-bis-N,N′-(2-oxybenzyl)-1,3-propan ediaminato](μ-asetato) nickel(II)}nickel(II)

Tatar Yildirim L., ATAKOL O.

Crystal Research and Technology, vol.37, no.12, pp.1352-1359, 2002 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 37 Issue: 12
  • Publication Date: 2002
  • Doi Number: 10.1002/crat.200290013
  • Journal Name: Crystal Research and Technology
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1352-1359
  • Keywords: Crystal structure, Elemental analysis, IR, NiII, Schiff base, Thermal analysis, Trinuclear complex
  • Hacettepe University Affiliated: Yes

Abstract

The title compound, a homotrinuclear NiII complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17TH20N2O2) (C3H7NO)}2], was identified using elemental analysis, thermal analysis, IR spectroscopy and x-ray diffraction techniques. It was established that although some bond lengths and angles changed with respect to previous complexes, the Ni...NJ distance was approximately the same.