Syntheses and characterizations of tetracyanoplatinate(II) complexes with 2-pyridineethanol

Sayin E., Kurkcuoglu G. S., Yesilel O. Z., HÖKELEK T.

JOURNAL OF COORDINATION CHEMISTRY, cilt.68, sa.13, ss.2271-2285, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 68 Sayı: 13
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1080/00958972.2015.1048239
  • Dergi Adı: JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2271-2285
  • Hacettepe Üniversitesi Adresli: Evet

Özet

New cyanide-bridged heteronuclear polymeric complexes, [Cu(hepH) 2Pt(mu-CN) 2(CN) 2] n (1), [ Zn (hepH) 2Pt(mu-CN)(2)(CN)(2)] n (2), and [ Cd(hepH)(2)Pt(mu-CN)(2)(CN)(2)] n (3) (2-pyridineethanol abbreviated to hepH), have been synthesized and characterized by elemental analysis, FT-IR and Raman spectroscopies, thermal analysis, and single-crystal X-ray diffraction techniques. Hydrogen bonds play very important roles in the construction of supramolecular structures. From the crystallographic data, it was determined that the crystal packings of 1-3 were composed of rare intermolecular C-H. Pt interactions. In addition, these complexes have p. p and O-H. N interactions.