AN INFRARED AND RAMAN-SPECTROSCOPIC STUDY OF TD-TYPE 4,4'-BIPYRIDYLCADMIUM(II) TETRACYANOMETALLATE(II) BENZENE(1/2) CLATHRATES - CD(C10H8N2)CD(CN)4.2C6H6 AND CD(C10H8N2)HG(CN)4.2C6H6

BAYARI S., KANTARCI Z., AKYUZ S.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, cilt.17, sa.3, ss.291-302, 1994 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 17 Sayı: 3
  • Basım Tarihi: 1994
  • Doi Numarası: 10.1007/bf00708788
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.291-302
  • Anahtar Kelimeler: HOFMANN-TD-TYPE CLATHRATE, CD-BIPYRIDYL TETRACYANOMETALLATE COMPLEXES, 4,4'-BIPYRIDYL BENZENE INCLUSION COMPOUNDS, IR AND RAMAN SPECTRA, CRYSTAL-STRUCTURES, CADMIUM CYANIDE, COMPLEXES, TRANSITION, FRAMEWORKS, HOST
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Two new benzene clathrates of the form Cd(4,4'-bipyridyl)M(CN)4 . 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.