AN INFRARED AND RAMAN-SPECTROSCOPIC STUDY OF TD-TYPE 4,4'-BIPYRIDYLCADMIUM(II) TETRACYANOMETALLATE(II) BENZENE(1/2) CLATHRATES - CD(C10H8N2)CD(CN)4.2C6H6 AND CD(C10H8N2)HG(CN)4.2C6H6

BAYARI S., KANTARCI Z., AKYUZ S.

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, vol.17, no.3, pp.291-302, 1994 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 17 Issue: 3
  • Publication Date: 1994
  • Doi Number: 10.1007/bf00708788
  • Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.291-302
  • Keywords: HOFMANN-TD-TYPE CLATHRATE, CD-BIPYRIDYL TETRACYANOMETALLATE COMPLEXES, 4,4'-BIPYRIDYL BENZENE INCLUSION COMPOUNDS, IR AND RAMAN SPECTRA, CRYSTAL-STRUCTURES, CADMIUM CYANIDE, COMPLEXES, TRANSITION, FRAMEWORKS, HOST
  • Hacettepe University Affiliated: Yes

Abstract

Two new benzene clathrates of the form Cd(4,4'-bipyridyl)M(CN)4 . 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.