Structure and electrochemical behaviour of Bis[N-(4-methylphenyl)salicylaldimine]copper(II) N,N '-dimethylformamide solvate

Yildirim L., EMREGUL K. C., KURTARAN R., ATAKOL O.

CRYSTAL RESEARCH AND TECHNOLOGY, vol.37, no.12, pp.1344-1351, 2002 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 37 Issue: 12
  • Publication Date: 2002
  • Doi Number: 10.1002/crat.200290012
  • Journal Name: CRYSTAL RESEARCH AND TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1344-1351
  • Hacettepe University Affiliated: Yes

Abstract

The molecular model of mononuclear complex formed, through a reaction between N-(4-methylphenyl)salicylaldimine and Cu-II ion was determined using x-ray diffraction method. The Cu-II coordination was found to have a distorted square-planar structure and a cis coordination geometry was observed within the surrounding of the copper. The electro chemical behaviour of the mononuclear copper complex was studied with cyclic voltammetry.