ILWENSISAPONIN-A, ILWENSISAPONIN-B, ILWENSISAPONIN-C, AND ILWENSISAPONIN-D - TRITERPENE SAPONINS FROM SCROPHULARIA-ILWENSIS

çalış i., ZOR M., BASARAN A. A., WRIGHT A., STICHER O.

HELVETICA CHIMICA ACTA, cilt.76, sa.3, ss.1352-1360, 1993 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76 Sayı: 3
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1002/hlca.19930760322
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1352-1360
  • Hacettepe Üniversitesi Adresli: Evet

Özet

From the aerial parts of Scrophularia ilwensis, four new triterpene saponins, ilwensisaponins A-D (1-4) were isolated. The structures of the compounds were elucidated using chemical and spectral data as 13beta,28-epoxy-3-beta {{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}olean-11-en-23-ol (1), 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}oleana-11,13(18)-diene-23,28-diol (2), 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}-11alpha-methoxyolean-12-ene-23,28-diol (3), and 3-beta-{{[beta-D-glucopyranosyl-(1 --> 2)]-[alpha-L-rhamnopyranosyl-(1 --> 4)-beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranosyl}oxy}olean-12-ene-11alpha,23,28-triol (4).