Synthesis, electrochemical and spectroscopic properties of ferrocene-based compounds

TAŞKOR ÖNEL G., ÖZGÜL KARAASLAN E., Osken I., SAYGILI N.

CHEMICAL PAPERS, cilt.76, sa.4, ss.2249-2257, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76 Sayı: 4
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1007/s11696-021-02034-7
  • Dergi Adı: CHEMICAL PAPERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Sayfa Sayıları: ss.2249-2257
  • Anahtar Kelimeler: Ferrocene derivatives, Palladium catalyst, Cross-coupling, UV-vis spectroscopy, Cyclic voltammetry, STRUCTURAL-CHARACTERIZATION, ETHYL-ESTERS, DERIVATIVES, ACID, COMPLEXES, CHEMISTRY, CRYSTAL, LIGANDS
  • Hacettepe Üniversitesi Adresli: Evet

Özet

Ferrocene derivatives have been synthesized by the Suzuki cross-coupling reaction of ferroceneboronic acid with various aryl/heteroaryl halides. The reactions yield ferrocenyl derivatives with overall yields varying between 35 and 98%. The derivatives have been characterized by (HNMR)-H-1, C-13 NMR, IR, HRMS and elemental analysis. The structure-property relationship has been investigated based on UVNis spectroscopy and cyclic voltammetry. Cyclic voltammetry studies revealed when the side group of ferrocenes were an electron-donating, lower oxidation was displayed. On the other hand, the strong electron-withdrawing group had a higher oxidation potential.