An infrared spectroscopic study of pyrazine- and 4,4 '-bipyridyl-T-d-type clathrates: Mn (pyrazine) M(CN)(4) benzene (M = Cd or Hg) and Mn (4,4 '-bipyridyl) M(CN)(4). benzene (M = Zn, Cd or Hg)
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.39, pp.115-121, 2001 (Journal Indexed in SCI)
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JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
The infrared spectra of the title compounds have been reported. The spectral data suggest that the host framework of these compounds are similar to those of the en-T-d-type clathrate compounds. There is good evidence for hydrogen bonding from ligand molecules to benzene molecules as a pi to sigma hydrogen bond.