Vibrational Spectroscopic Studies on the T-d-type N,N '-dimethylethylenediamine(II)tetracyanometallate(II) Benzene Clathrates


Bayrak C.

ASIAN JOURNAL OF CHEMISTRY, vol.22, no.5, pp.3734-3740, 2010 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 22 Issue: 5
  • Publication Date: 2010
  • Title of Journal : ASIAN JOURNAL OF CHEMISTRY
  • Page Numbers: pp.3734-3740

Abstract

FT-IR spectra of Mn(DMEDA)M(CN)(4) C6H6, (M = Zn. Cd or Hg, DMEDA = N,N'-dimethylethylenediamine) and FT-IR and FT-Raman spectra of Cd(DMEDA)M(CN)(4) C6H6(M = Cd or Hg) are reported. All the vibrational modes of coordinated DMEDA are characterized The spectral features suggest that these compounds are similar in structure to the Hofmann-T-d-type clathrates.